A close-up of Saturn, rings, and moons on encounter day
Due to trajectory constrains, Pioneer approached and receded from Saturn looking at the backlit side of the rings, something never seen from earth except briefly when the rings are nearly edge on during ring plane crossings. Thus its view was interesting but also unfamiliar.
Approaching Saturn (with Titan)
Receding from Saturn. Due to data rate constraints, only every other pixel was returned, hence the reduced quality.
Best view of the unlit side of the rings during approach
During closest approach, Pioneer briefly passed through the ring plane and back, in theory giving it a view of the sunlit side of the rings. Given the speed at which it was traveling and that it's scanning imager, which built up images one pixel at a time using the spin of the spacecraft, took a long time to assemble pictures, not much could be done with this. The instrument did have, however, a lower resolution mode that was for the purpose of polarization studies, which could only take very crude images (if they could be called that). It could, however, work fast enough to capture the fleeting view. Here is an example of one.
The daylit side of the rings in front of the panet, with the limb visible behind them.
These images can be built up into a pretty nifty model of the rings.
The day side of Saturn's rings using data from Pioneer 11 in polarization mode